Mueller testified under oath. Statements of fact fall under the rules of perjury.
He has just testified that he met with POTUS and discussed the position of Attorney General. He said as a matter of fact that he did so not as a candidate for that position. This claim introduced a dispute of fact.
He has also testified that he does not remember if, during that same meeting, he discussed the firing of Comey. The fact at issue here is not whether or not he did discussed the firing, but that he claims to not remember whether or not he did so.
That this would have disqualified him at the outset is of enormous significance to his acceptance of the job offer from RR, as this would constitute a clear conflict of interest directly bearing on the investigation itself.
These statements of fact (plus the underlying need to fact-find about what was discussed in the meeting with POTUS) open Mueller up to questioning beyond his written reports (vol 1 and vol 2). He is before the Judiciary Committee of the House and his credibility is on the front burner now. As Grassley forewarned just before this moment in Mueller's testimony.
As a strategic and procedural matter, this has given the Republicans an edge. How they pursue it on the House committee – or on the Senate committee – is up to them. Think of it as gaining the advantage in a set during a tennis match.