When mobilized (or activated) under Title 10 U.S.C., you are directed by the president to report for active duty in an official capacity. You are being activated for federal active-duty military service. When in federal service, Guard personnel typically participate in military operations and are entitled to the same pay, benefits and legal protections as active military members.
Activation under Title 32 U.S.C. means that your state's governor has been authorized or directed by the president to mobilize or activate the National Guard in your state. You perform on active duty under state control, but with pay and benefits provided by the federal government. As long as your Title 32 orders are for more than 30, you are still entitled to the same federal benefits as someone activated under Title 10 orders.