National Guard call up title 10 vs 32
When mobilized (or activated) under Title 10 U.S.C., you are directed by the president to report for active duty in an official capacity. You are being activated for federal active-duty military service. When in federal service, Guard personnel typically participate in military operations and are entitled to the same pay, benefits and legal protections as active military members.
Activation under Title 32 U.S.C. means that your state's governor has been authorized or directed by the president to mobilize or activate the National Guard in your state. You perform on active duty under state control.
Mobilization orders may come with different duties. Title 10 service can include overseas mobilizations; Title 32 does not. Normally, Title 32 orders are for natural disasters, while Title 10 orders are for national defense. However, this isn't always the case.
https://www.military.com/benefits/reserve-and-guard-benefits/whats-difference-between-title-10-and-title-32-mobilization-orders.html